Synthesis of Functionalized Polythiophene as a Potenial Organic Semi-Conductor

Synthesis of Functionalized Aryl-vinyl Ethers as Building Blocks and Auxiliaries in Organic Synthesis

5- hydroxyisoquinoline undergoes a smooth reaction with alkyl propiolates in the presence of triphenylphosphine (15 mol%) to produce the corresponding (E)-alkyl 3-(isoquinolin-5-yloxy) acrylate in good yields. When the reaction was performed by 2-methyl 4-hydroxyquinoline and 3-nitro 4-hydroxypyridine, similar aryl vinyl ethers were obtained.

Synthesis of Functionalized Organic Nanostructures

synthesis of functionalized aryl-vinyl ethers as building blocks and auxiliaries in organic synthesis

Azine- and Azole-Functionalized Oligo´ and Polythiophene Semiconductors for Organic Thin-Film Transistors

In the organic electronics research field, several strategies have been used to modulate the transport properties of thiophene-derived semiconductors via sequential functionalization of their π-conjugated cores. This review summarizes the major design and synthetic strategies for tuning thiophene-containing small molecule and polymer properties by introducing electron-deficient nitrogen-contain...

Distonic Radical Anions Generated via Single Electron Transfer and Their Potenial In Organic Synthesis

Herein, recent developments in the production and reactivity of distonic radical anions are reviewed. Known and potential reactions utilizing both the radical and anion centers are highlighted. While work has revealed new distonic radical anion species, limited effort has been to apply them to complex molecule synthesis. Through the development of new photoinduced electron transfer reagents, di...